Liquid-based Batteries Could Run On Fluorescent Dye
A glow-in-the-dark dye be the next advancement in energy storage technology, say scientists at the University at Buffalo. They have fingered a fluorescent dye called boron-dipyrromethene as an ideal material for stockpiling energy in rechargeable, liquid-based batteries that could one day power cars and homes.
Boron-dipyrromethene (BODIPY) shines brightly in the dark under a black light, but the features that facilitate energy storage are less visible.
According to new research, the dye has unusual chemical properties that enable it to excel at two key tasks: storing electrons and participating in electron transfer. Batteries must perform these functions to save and deliver energy, and BODIPY is very good at them.
Redox Flow Batteries
In experiments, a BODIPY-based test battery operated efficiently and with longevity, running well after researchers drained and recharged it 100 times.
Lead researcher Timothy Cook, PhD, an assistant professor of chemistry in the University at Buffalo College of Arts and Sciences, said:
“As the world becomes more reliant on alternative energy sources, one of the huge questions we have is, ‘How do we store energy?’ What happens when the sun goes down at night, or when the wind stops? All these energy sources are intermittent, so we need batteries that can store enough energy to power the average house.”
BODIPY is a promising material for a liquid-based battery called a “redox flow battery.”
These fluid-filled power cells present several advantages over those made from conventional materials.
Lithium-ion batteries, for example, are risky in that they can catch fire if they break open, Cook says. The dye-based batteries would not have this problem; if they ruptured, they would simply leak, he says.
To make the dye solution used in the test battery, the research team mixed dark red BODIPY crystals (right) into a clear solvent called acetonitrile (left). Credit: Douglas Levere
Redox flow batteries can also be easily enlarged to store more energy, enough to allow a homeowner to power a solar house overnight, for instance, or to enable a utility company to stockpile wind energy for peak usage times. This matters because scaling up has been a challenge for many other proposed battery technologies.
How A Boron-dipyrromethene Battery Works
Redox flow batteries consist of two tanks of fluids separated by various barriers.
When the battery is being used, electrons are harvested from one tank and moved to the other, generating an electric current that—in theory—could power devices as small as a flashlight or as big as a house.
To recharge the battery, you would use a solar, wind or other energy source to force the electrons back into the original tank, where they would be available to do their job again.
First author Anjula M. Kosswattaarachchi, a UB PhD student in chemistry, holds a volumetric flask containing BODIPY dye. Credit: Douglas Levere
A redox flow battery’s effectiveness depends on the chemical properties of the fluids in each tank.
“The library of molecules used in redox flow batteries is currently small but is expected to grow significantly in coming years,” Cook says. “Our research identifies BODIPY dye as a promising candidate.”
In experiments, Cook’s team filled both tanks of a redox flow battery with the same solution: a powdered BODIPY dye called PM 567 dissolved in liquid.
Within this cocktail, the BODIPY compounds displayed a notable quality.
They were able to give up and receive an electron without degrading as many other chemicals do. This trait enabled the dye to store electrons and facilitate their transfer between the battery’s two ends during repeated cycles—100—of charging and draining.
Based on the experiments, scientists also predict that BODIPY batteries would be powerful enough to be useful to society, generating an estimated 2.3 volts of electricity.
The study focused on PM 567, different varieties of BODIPY share chemical properties, so it’s likely that other BOPIDY dyes would also make good energy storage candidates, Cook says.